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A Levels Chemistry (9701)•9701/13/M/J/20
Question 34 from 9701/13/M/J/20

Explanation

Activation Energy in Reversible Reactions

Steps:

  • Recall activation energy (Ea) is the minimum energy required for effective collisions to form products.
  • Note catalysts like iron lower Ea for both forward and reverse reactions equally in equilibrium systems.
  • Compare Ea for forward (higher) and reverse (lower by ΔH) reactions in exothermic Haber process.
  • Evaluate statements: A mismatches Ea values; B and D ignore equal catalyst effect; C matches definition.

Why C is correct:

  • Activation energy is defined as the minimum kinetic energy colliding particles need to overcome the energy barrier and react, per collision theory.

Why the others are wrong:

  • A: Ea forward exceeds Ea reverse by the exothermic reaction's enthalpy change (ΔH < 0).
  • B: Iron catalyst reduces Ea for both directions equally, not just forward.
  • D: Iron decreases Ea for reverse reaction equally with forward, maintaining equilibrium.

Final answer: C

Topic: Reaction kinetics

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