A Levels Chemistry (9701)•9701/13/M/J/20

Explanation
Sodium's reactivity with both alcoholic and carboxylic OH groups
Steps:
- Lactic acid, CH₃CH(OH)COOH, contains an alcoholic -OH (secondary) and a carboxylic -OH.
- Sodium metal reduces to Na⁺ and releases H₂ when reacting with acidic hydrogens.
- It deprotonates the alcoholic -OH to form CH₃CH(ONa)COOH + ½H₂.
- It also deprotonates the carboxylic -OH to form CH₃CH(OH)COONa + ½H₂, consuming both.
Why C is correct:
- Sodium reacts with alcohols (ROH + Na → RONa + ½H₂) and carboxylic acids (RCOOH + Na → RCOONa + ½H₂), engaging both -OH types via redox with H.
Why the others are wrong:
- A: Oxidizes the alcoholic -OH to a carbonyl (CH₃COCOOH) but leaves carboxylic -OH unchanged.
- B: Esterifies only the carboxylic -OH (to ethyl lactate) under catalysis, ignoring alcoholic -OH.
- D: Neutralizes only the carboxylic -OH (to CH₃CH(OH)COO⁻ Na⁺), sparing alcoholic -OH.
Final answer: C
Topic: Hydroxy compounds
Practice more A Levels Chemistry (9701) questions on mMCQ.me