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A Levels Chemistry (9701)•9701/13/M/J/20
Question 16 from 9701/13/M/J/20

Explanation

Catalytic Converters Reduce NOx via Heterogeneous Catalysis

Steps:

  • NOx removal occurs in catalytic converters using a solid catalyst with gaseous exhaust.
  • Catalysts lower activation energy to speed up reactions without being consumed.
  • The process involves heterogeneous catalysis, as reactants (gases) differ in phase from the catalyst (solid).
  • Thus, the catalyst decreases activation energy through heterogeneous means.

Why A is correct:

  • Catalysts decrease activation energy per transition state theory; catalytic converters use heterogeneous catalysis with platinum/rhodium on a ceramic support.

Why the others are wrong:

  • B: Homogeneous catalysis requires same-phase catalyst/reactants, but converter uses solid-gas phases.
  • C: Catalysts decrease, not increase, activation energy.
  • D: Combines incorrect increase in activation energy with wrong homogeneous type.

Final answer: A

Topic: Reaction kinetics

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