A Levels Chemistry (9701)•9701/13/M/J/20

Explanation
Trends in Group 2 Properties Down the Group
Steps:
- Atomic number increases down Group 2, adding electron shells and increasing atomic size.
- Ionic radius of +2 ions increases due to more shells while maintaining charge, weakening effective nuclear attraction.
- First ionisation energy decreases as outer electrons are farther from the nucleus with increased shielding.
- Atomic radius increase correlates with decreasing ionisation energy, not increasing.
Why A is correct:
- Down Group 2, more electron shells increase the size of M²⁺ ions, as per the trend in periodic table groups.
Why the others are wrong:
- B: First ionisation energy decreases down the group due to larger atomic size and shielding effects.
- C: This statement is actually correct; first ionisation energy decreases with increasing atomic number in Group 2.
- D: As atomic radius increases down the group, first ionisation energy decreases, following the inverse relationship from atomic structure.
Final answer: A and C
Topic: Group 2
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