A Levels Chemistry (9701)•9701/12/M/J/20

Explanation
Cyanohydrin formation introduces a nitrile group detectable by IR
Steps:
- Propanal, an aldehyde, reacts with HCN to form a cyanohydrin: CH₃CH₂CH(OH)CN.
- The product features a nitrile (-C≡N) functional group.
- IR spectroscopy identifies functional groups via characteristic stretching frequencies.
- The -C≡N stretch appears as a weak band in the 2200-2500 cm⁻¹ region.
Why A is correct:
- Nitrile C≡N triple bond stretching vibration produces a weak absorption at 2200-2500 cm⁻¹, per standard IR correlation tables.
Why the others are wrong:
- B: 3200-3600 cm⁻¹ indicates O-H stretch from the hydroxyl group, but this is not unique to the reaction product.
- C: 1040-1300 cm⁻¹ corresponds to C-O stretch in alcohols, present but not diagnostic for the cyanohydrin formation.
Final answer: A
Topic: Carbonyl compounds
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