A Levels Chemistry (9701)•9701/12/M/J/20

Explanation
Pressure Effects on Rate and Yield in Haber Process Steps:
- Reaction is exothermic (ΔH negative), so decreasing temperature shifts equilibrium right (higher NH₃ yield) but slows rate by reducing kinetic energy.
- Increasing pressure shifts equilibrium right (fewer gas moles on product side) per Le Chatelier's principle, increasing yield; it also raises reactant concentrations, speeding up rate via more collisions.
- Increasing catalyst surface area provides more active sites, accelerating rate without altering equilibrium position or yield.
- No option D provided, so evaluate A–C only.
Why B is correct:
- Higher pressure increases both rate (higher concentration speeds collisions) and yield (Le Chatelier's principle favors fewer moles).
Why the others are wrong:
- A decreases rate while increasing yield.
- C increases rate but leaves yield unchanged (catalysts speed attainment of equilibrium, not position).
Final answer: B
Topic: Equilibria
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