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A Levels Chemistry (9701)•9701/12/M/J/20
Question 27 from 9701/12/M/J/20

Explanation

Enumerating structural isomers of esters with formula C4H8O2

Steps:

  • Esters follow RCOOR' formula; total carbons in R + R' +1 (carbonyl) =4.
  • Formate esters (R=H, R'=C3H7): n-propyl formate (HCOOCH2CH2CH3) and isopropyl formate (HCOOCH(CH3)2).
  • Acetate esters (R=CH3, R'=C2H5): ethyl acetate (CH3COOCH2CH3).
  • Propanoate esters (R=C2H5, R'=CH3): methyl propanoate (CH3CH2COOCH3).
  • No other combinations yield C4H8O2 for saturated carboxylate esters.

Why C is correct:

  • Exactly four structural isomers exist, as confirmed by partitioning the carbon chain across acid and alcohol moieties.

Why the others are wrong:

  • A. 2: Underestimates by ignoring chain and branching variants.
  • B. 3: Misses isopropyl formate isomer.
  • D. 5: Overcounts; no additional saturated ester fits the formula.

Final answer: C

Topic: Carboxylic acids and derivatives

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