A Levels Chemistry (9701)•9701/12/M/J/20

Explanation
Enumerating structural isomers of esters with formula C4H8O2
Steps:
- Esters follow RCOOR' formula; total carbons in R + R' +1 (carbonyl) =4.
- Formate esters (R=H, R'=C3H7): n-propyl formate (HCOOCH2CH2CH3) and isopropyl formate (HCOOCH(CH3)2).
- Acetate esters (R=CH3, R'=C2H5): ethyl acetate (CH3COOCH2CH3).
- Propanoate esters (R=C2H5, R'=CH3): methyl propanoate (CH3CH2COOCH3).
- No other combinations yield C4H8O2 for saturated carboxylate esters.
Why C is correct:
- Exactly four structural isomers exist, as confirmed by partitioning the carbon chain across acid and alcohol moieties.
Why the others are wrong:
- A. 2: Underestimates by ignoring chain and branching variants.
- B. 3: Misses isopropyl formate isomer.
- D. 5: Overcounts; no additional saturated ester fits the formula.
Final answer: C
Topic: Carboxylic acids and derivatives
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