A Levels Chemistry (9701)•9701/12/M/J/20

Explanation
Damascenone has one stereogenic double bond
Steps:
- Inspect structure for chiral centers: none, as all carbons have incorrect substitution for chirality.
- Locate double bonds: one trisubstituted alkene in the side chain allows E/Z configuration.
- Count stereogenic units: single unit yields 2 geometric isomers.
- Total stereoisomers including damascenone: 2.
Why B is correct:
- One stereogenic double bond produces 2 geometric isomers, as defined by alkene stereoisomerism where restricted rotation creates distinct configurations.
Why the others are wrong:
- A: Overlooks the E/Z isomerism of the double bond.
- C: Assumes two stereogenic units, but only one exists.
- D: Implies three units, exceeding the molecule's single double bond.
Final answer: B
Topic: An introduction to organic chemistry
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