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A Levels Chemistry (9701)•9701/12/M/J/20
Question 21 from 9701/12/M/J/20

Explanation

Carbonyl group IR absorption Steps:

  • The 1610–1750 cm⁻¹ range indicates strong C=O stretching vibration in carbonyl compounds.
  • Identify functional groups from molecular formulas, ensuring no cyclic structures.
  • P (CH₄O): Possible structure is CH₃OH (methanol), an alcohol with O–H but no C=O.
  • Q (CH₂O): Structure is H₂C=O (formaldehyde), an aldehyde with C=O.
  • R (C₂H₄O): Structure is CH₃CHO (acetaldehyde), an aldehyde with C=O. Why C is correct:
  • Q and R contain carbonyl groups, which produce strong C=O absorption per IR spectroscopy principles for C=O stretch. Why the others are wrong:
  • A: Excludes R, but R has a carbonyl.
  • B: Excludes Q, but Q has a carbonyl.
  • D: Includes P, but P lacks a carbonyl.

Final answer: C

Topic: Analytical techniques

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