A Levels Chemistry (9701)•9701/11/M/J/20

Explanation
Decomposition of Mg(NO3)₂ yields 2.5 mol gas per mol compound Steps:
- Molar mass of Mg(NO₃)₂ = 24 + 2(14) + 6(16) = 148 g/mol.
- Moles of Mg(NO₃)₂ = 0.25 / 148 ≈ 0.00169 mol.
- Reaction: Mg(NO₃)₂ → MgO + 2NO₂ + ½O₂ (2.5 mol gas/mol compound); moles gas = 0.00169 × 2.5 ≈ 0.00423 mol.
- At room conditions (≈24 L/mol = 24,000 cm³/mol), volume = 0.00423 × 24,000 ≈ 101 cm³. Why C is correct:
- Stoichiometry and ideal gas law with 24 L/mol molar volume give ≈100 cm³ total gas (NO₂ + O₂). Why the others are wrong:
- A: Underestimates gas by ignoring full NO₂ yield (≈1 mol gas/mol).
- B: Matches only NO₂ volume, ignores O₂ contribution.
- D: Overestimates by doubling gas moles (e.g., extra O₂).
Final answer: C
Topic: Group 2
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