A Levels Chemistry (9701)•9701/13/M/J/19

Explanation
Ideal gases behave ideally with negligible intermolecular forces
Steps:
- Recall ideal gas law: PV = nRT assumes point particles with no interactions.
- Identify deviations: Real gases deviate due to intermolecular forces and molecular volume.
- Evaluate conditions: High pressure and low temperature enhance attractions, increasing deviations.
- Assess properties: Weaker forces reduce attractions, making behavior closer to ideal.
Why D is correct:
- Ideal gas model defines gases as having zero intermolecular forces; weaker forces minimize deviations from PV = nRT.
Why the others are wrong:
- A: Higher pressure compresses molecules, amplifying intermolecular attractions and volume effects.
- B: Lower temperature slows molecules, strengthening relative impact of attractive forces.
- C: More polar molecules increase dipole-dipole attractions, causing larger deviations.
Final answer: D
Topic: States of matter
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