A Levels Chemistry (9701)•9701/13/M/J/19

Explanation
SN1 Mechanism Features Stabilized Carbocation Intermediate
Steps:
- Haloalkane undergoes heterolytic cleavage of C-X bond, forming a carbocation intermediate.
- Carbocation stability increases with adjacent alkyl groups via hyperconjugation and inductive effects.
- Nucleophile then attacks the planar carbocation from either side.
- Rate-determining step is carbocation formation, leading to racemization.
Why C is correct:
- In SN1, the carbocation intermediate follows Zaitsev's rule analog, where adjacent alkyl groups donate electrons to stabilize the positive charge through hyperconjugation.
Why the others are wrong:
- A: SN1 involves nucleophilic attack on the carbocation, not substitution of nucleophile by electrophile.
- B: The carbocation forms from unimolecular dissociation of one haloalkane molecule.
- D: The intermediate is a positively charged carbocation, not uncharged.
Final answer: C
Topic: Halogen compounds
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