A Levels Chemistry (9701)•9701/12/M/J/19

Explanation
Hydrolysis of chlorine oxide yielding 1:5 HCl to HClO ratio Steps:
- Products require 6 Cl atoms for 1 HCl + 5 HClO.
- ClO₂ supplies 1 Cl per molecule, so 6 ClO₂ provide 6 Cl and 12 O.
- Add 3 H₂O for 6 H and 3 O; products use 5 O, leaving 10 O as 5 O₂.
- Equation 6 ClO₂ + 3 H₂O → HCl + 5 HClO + 5 O₂ balances Cl, H, O.
Why C is correct:
- ClO₂ disproportionates in water to HCl (-1 oxidation state) and HClO (+1), with stoichiometry matching 1:5 ratio per balanced equation.
Why the others are wrong:
- A. Cl₂: Equilibrium reaction Cl₂ + H₂O ⇌ HCl + HClO gives 1:1 ratio.
- B. ClO: Unstable radical with no defined hydrolysis to these acids.
- D. Cl₂O: Reacts as Cl₂O + H₂O → 2 HClO, producing only HClO.
Final answer: C
Topic: Group 17
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