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A Levels Chemistry (9701)•9701/12/M/J/19
Question 33 from 9701/12/M/J/19

Explanation

Nitrogen reduction via decreased oxidation state Steps:

  • Calculate oxidation state of N in reactants and products for each reaction.
  • Reduction occurs when N's oxidation state decreases.
  • In option A, N in NO is +2 (O is -2); in N₂, N is 0—decreases to 0.
  • Options B–D show no decrease or increase in N's oxidation state.

Why A is correct:

  • N's oxidation number decreases from +2 to 0, defining reduction as a loss of oxidation number (or gain of electrons).

Why the others are wrong:

  • B: N's oxidation state stays +2 in NO and NH₃ (no change).
  • C: N's oxidation state increases from +4 in NO₂ to +2 in NO (oxidation).
  • D: N's oxidation state increases from +4 in NO₂ to -3 in NH₃ (but overall oxidation due to H₂).

Final answer: A

Topic: Nitrogen and sulfur

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