A Levels Chemistry (9701)•9701/12/M/J/19

Explanation
IR spectrum identifies ketone via carbonyl stretch without O-H band
Steps:
- Examine spectrum for broad O-H stretch (3200–3600 cm⁻¹), absent in Q, ruling out alcohols and acids.
- Identify strong C=O stretch around 1710–1715 cm⁻¹, indicating carbonyl group.
- Note absence of aldehyde C-H stretches (2700–2800 cm⁻¹), narrowing to ketone.
- Match to butanone's expected IR profile for C4H8O ketone.
Why C is correct:
- Butanone features isolated C=O stretch at 1710–1715 cm⁻¹ per Hooke's law for ketone vibration, without O-H interference.
Why the others are wrong:
- A: Butan-1-ol shows broad O-H stretch from hydrogen bonding, missing in Q's spectrum.
- B: Butanoic acid exhibits broad O-H and C=O at ~1710 cm⁻¹ with C-O bands, not matching Q.
- D: 3-Hydroxybutanal has broad O-H and aldehyde C-H stretches, absent in Q.
Final answer: C
Topic: Analytical techniques
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