A Levels Chemistry (9701)•9701/11/M/J/19

Explanation
Polyalkenes lack reactive double bonds Steps:
- Identify polyalkenes as addition polymers from alkene monomers, forming long chains of single C-C bonds (saturated).
- Test statement A: Saturated hydrocarbons do not undergo electrophilic addition with Br₂ without UV light or catalysts.
- Test statement B: Complete combustion of polyalkenes (CₙH₂ₙ₊₂-like) yields only CO₂ and H₂O, standard products not classified as harmful.
- Test statement C: While slow, some polyalkenes biodegrade under specific conditions; "do not readily" overstates inertness.
Why A is correct:
- Polyalkenes have no C=C bonds, so they do not react with Br₂ in the dark via addition (unlike alkenes, per Markovnikov's rule).
Why the others are wrong:
- B: Combustion produces non-toxic CO₂ and H₂O in ideal conditions; "harmful products" implies pollutants like those from halogenated polymers.
- C: Polyalkenes degrade slowly via oxidation or microbial action but do so eventually; statement ignores partial biodegradability.
Final answer: A
Topic: Polymerisation
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