A Levels Chemistry (9701)•9701/11/M/J/19

Explanation
Bonding in ammonium chloride
Steps:
- Identify the reaction: NH₃ + HCl → NH₄Cl, forming ammonium ion.
- Break down NH₄Cl structure: ionic between NH₄⁺ and Cl⁻, internal bonds in NH₄⁺.
- Analyze NH₄⁺: tetrahedral with four N-H bonds, one formed by coordinate donation.
- Check geometry: NH₄⁺ has 109.5° angles; test other reactions.
Why B is correct:
- NH₄Cl features ionic bond (NH₄⁺—Cl⁻), three covalent N-H bonds, and one coordinate bond (N lone pair to H⁺), per VSEPR and Lewis theory.
Why the others are wrong:
- A: Ammonia forms ammonium salts with acids, not isolated ammonium ion.
- C: NH₄⁺ reacts with bases (e.g., OH⁻) to yield NH₃, not acids.
- D: Tetrahedral NH₄⁺ has 109.5° bond angles, not 107°.
Final answer: B
Topic: Nitrogen and sulfur
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