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A Levels Chemistry (9701)•9701/11/M/J/19
Question 19 from 9701/11/M/J/19

Explanation

Bonding in ammonium chloride

Steps:

  • Identify the reaction: NH₃ + HCl → NH₄Cl, forming ammonium ion.
  • Break down NH₄Cl structure: ionic between NH₄⁺ and Cl⁻, internal bonds in NH₄⁺.
  • Analyze NH₄⁺: tetrahedral with four N-H bonds, one formed by coordinate donation.
  • Check geometry: NH₄⁺ has 109.5° angles; test other reactions.

Why B is correct:

  • NH₄Cl features ionic bond (NH₄⁺—Cl⁻), three covalent N-H bonds, and one coordinate bond (N lone pair to H⁺), per VSEPR and Lewis theory.

Why the others are wrong:

  • A: Ammonia forms ammonium salts with acids, not isolated ammonium ion.
  • C: NH₄⁺ reacts with bases (e.g., OH⁻) to yield NH₃, not acids.
  • D: Tetrahedral NH₄⁺ has 109.5° bond angles, not 107°.

Final answer: B

Topic: Nitrogen and sulfur

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