A Levels Chemistry (9701)•9701/11/M/J/19

Explanation
Substance X as Barium Metal from Reaction Products
Steps:
- Substance X reacts with water to produce a gas (hydrogen) and increase pH, indicating a reactive metal forming a basic hydroxide solution.
- The solution, containing metal hydroxide ions, reacts with sulfuric acid to form a white precipitate, identifying an insoluble sulfate like BaSO4.
- Barium metal fits: Ba + 2H2O → Ba(OH)2 + H2 (gas, basic solution).
- Adding H2SO4 to Ba(OH)2 yields BaSO4 precipitate, confirming barium.
Why A is correct:
- Barium metal reacts with water per the equation Ba + 2H2O → Ba(OH)2 + H2, producing gas and base; Ba2+ forms white, insoluble BaSO4 with H2SO4.
Why the others are wrong:
- B: Barium oxide (BaO + H2O → Ba(OH)2) produces no gas with water.
- C: Magnesium oxide (MgO + H2O → Mg(OH)2) produces no gas; MgSO4 is soluble, no precipitate.
- D: Identical to C, magnesium oxide fails both tests.
Final answer: A
Topic: Group 2
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