A Levels Chemistry (9701)•9701/11/M/J/19

Explanation
Maxwell-Boltzmann Distribution Broadens with Temperature Steps:
- Maxwell-Boltzmann distribution gives the fraction of molecules with kinetic energy E as proportional to √E exp(-E/kT).
- Most probable energy E_mp = ½ kT increases with T, but peak height g(E_mp) ∝ 1/T decreases as distribution spreads.
- Total molecules fixed, so number around E_mp drops due to lower peak density.
- For high E (E >> kT), fraction ∝ exp(-E/kT) rises with T, increasing molecules in high-energy tail.
Why C is correct:
- Peak density at E_mp scales as 1/T from the distribution formula, decreasing molecules there; high-energy tail grows via reduced -E/kT exponent.
Why the others are wrong:
- A: High-energy molecules increase, not decrease.
- B: Most probable energy molecules decrease, not increase; high-energy increases, not decrease.
- D: Most probable energy molecules decrease, not increase.
Final answer: C
Topic: States of matter
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