A Levels Chemistry (9701)•9701/13/M/J/18

Explanation
Ideal Gas Law: PV = nRT for fixed mass (n constant)
Steps:
- Apply ideal gas law: for fixed n, PV ∝ T.
- At constant volume, P ∝ T, yielding a straight line through origin on P-T graph.
- At constant pressure, V ∝ T, yielding a straight line through origin on V-T graph.
- Identify diagram showing linear relationship starting at T=0 K.
Why A is correct:
- Diagram A shows P or V linearly increasing with T from origin, matching PV = nRT where absolute zero corresponds to zero volume or pressure.
Why the others are wrong:
- B: Nonlinear curve violates direct proportionality in ideal gas law.
- C: Line doesn't pass through origin, ignoring T=0 K behavior.
- D: Decreasing trend contradicts expansion with rising temperature.
Final answer: A
Topic: States of matter
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