A Levels Chemistry (9701)•9701/13/M/J/18

Explanation
Evaluation of reaction mechanism statements Steps:
- Identify the reaction: propanone (ketone) + HCN forms cyanohydrin via nucleophilic addition.
- Analyze species roles: CN⁻ acts as nucleophile attacking electrophilic carbonyl carbon.
- Classify reaction type: addition across C=O π bond, forming tetrahedral intermediate.
- Examine bond changes: H-CN bond breaks heterolytically to generate CN⁻ and H⁺.
Why C is correct:
- Heterolytic bond breaking involves unequal electron distribution, as in H-CN → H⁺ + CN⁻, where the electron pair stays with CN per the definition of heterolysis.
Why the others are wrong:
- A: CN⁻ is a nucleophile (electron donor), not an electrophile (electron acceptor).
- B: The reaction is an addition, but the mechanism shown may depict a different classification; not enough information.
- D: Not enough information (statement incomplete).
Final answer: C
Topic: Carbonyl compounds
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