A Levels Chemistry (9701)•9701/12/M/J/18

Explanation
Halving enthalpy for half the water produced Steps:
- Reaction 1 uses 2 mol NaOH to form 2 mol H₂O with ΔH = -114 kJ mol⁻¹.
- Reaction 2 uses 1 mol NaOH to form 1 mol H₂O.
- Strong acid-strong base neutralizations have constant ΔH ≈ -57 kJ per mol H₂O.
- Divide reaction 1's ΔH by 2: -114 kJ / 2 = -57 kJ mol⁻¹ for reaction 2. Why A is correct:
- Matches standard neutralization enthalpy for 1 mol H⁺ + 1 mol OH⁻ → 1 mol H₂O. Why the others are wrong:
- B: -76 kJ mol⁻¹ lacks basis in stoichiometry or standard values.
- C: -114 kJ mol⁻¹ applies to 2 mol H₂O in reaction 1, not 1 mol.
- D: -228 kJ mol⁻¹ doubles reaction 1 incorrectly for 4 mol H₂O.
Final answer: A
Topic: Chemical energetics
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