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A Levels Chemistry (9701)•9701/12/M/J/18
Question 7 from 9701/12/M/J/18

Explanation

Halving enthalpy for half the water produced Steps:

  • Reaction 1 uses 2 mol NaOH to form 2 mol H₂O with ΔH = -114 kJ mol⁻¹.
  • Reaction 2 uses 1 mol NaOH to form 1 mol H₂O.
  • Strong acid-strong base neutralizations have constant ΔH ≈ -57 kJ per mol H₂O.
  • Divide reaction 1's ΔH by 2: -114 kJ / 2 = -57 kJ mol⁻¹ for reaction 2. Why A is correct:
  • Matches standard neutralization enthalpy for 1 mol H⁺ + 1 mol OH⁻ → 1 mol H₂O. Why the others are wrong:
  • B: -76 kJ mol⁻¹ lacks basis in stoichiometry or standard values.
  • C: -114 kJ mol⁻¹ applies to 2 mol H₂O in reaction 1, not 1 mol.
  • D: -228 kJ mol⁻¹ doubles reaction 1 incorrectly for 4 mol H₂O.

Final answer: A

Topic: Chemical energetics

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