A Levels Chemistry (9701)•9701/12/M/J/18

Explanation
Isothermal compression leaves Kp unchanged and mole fractions initially unaltered
Steps:
- Recognize that Kp depends solely on temperature; constant T means Kp unchanged.
- Note compression decreases volume, raising total pressure proportionally for all gases.
- Understand mole fraction of Z is moles Z divided by total moles, unaffected immediately by volume change.
- Conclude no shift in composition is implied without specifying re-equilibration time, so no change in mole fraction.
Why B is correct:
- Kp is defined as a function of temperature only (van't Hoff equation), and mole fractions depend on relative moles, which don't alter instantly upon compression.
Why the others are wrong:
- A: Kp cannot increase at constant T.
- C: Mole fraction of Z cannot decrease; compression favors no immediate drop.
- D: Identical to B, so not distinct.
Final answer: B
Topic: Equilibria
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