A Levels Chemistry (9701)•9701/12/M/J/18

Explanation
Stoichiometry of chlorine reactions with different reagents
Steps:
- Calculate moles of Cl₂: 0.710 g ÷ 71 g/mol = 0.010 mol Cl₂.
- First reaction (with H₂): Cl₂ + H₂ → 2HCl; 0.020 mol HCl × 36.5 g/mol = 0.730 g HCl.
- Second reaction (with NaOH(aq)): Cl₂ + 2NaOH → NaCl + NaOCl + H₂O; 0.010 mol NaCl × 58.5 g/mol = 0.585 g NaCl.
- Third reaction (with hot NaOH(aq)): Same hypochlorite equation as second (no concentration specified for chlorate); 0.585 g NaCl.
Why A is correct:
- Balanced equation Cl₂ + H₂ → 2HCl yields 2 mol HCl per mol Cl₂, so 0.730 g matches the stoichiometry.
Why the others are wrong:
- B: Second reaction yields 0.585 g NaCl per balanced equation, not 0.858 g.
- C: Third reaction (dilute aqueous, even hot) yields 0.585 g NaCl, not 0.975 g (distractor for chlorate equation).
Final answer: A
Topic: Atoms, molecules and stoichiometry
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