A Levels Chemistry (9701)•9701/11/M/J/18

Explanation
Fuel with highest carbon mass fraction produces most CO2 per kg
Steps:
- Calculate molar mass (M) for each fuel using atomic masses (C=12, H=1, O=16).
- Compute carbon mass fraction: (number of C atoms × 12) / M.
- Determine CO2 mass per kg fuel: carbon fraction × (44/12).
- Compare: octane (3.09 kg CO2/kg), propane (3.00 kg), biodiesel (2.80 kg), ethanol (1.91 kg).
Why C is correct:
- Octane has the highest carbon mass fraction (96/114 ≈ 0.842), maximizing CO2 via C + O₂ → CO₂ stoichiometry.
Why the others are wrong:
- A: Biodiesel's oxygen lowers carbon fraction (216/282 ≈ 0.766).
- B: Ethanol's high oxygen and hydrogen content yields lowest carbon fraction (24/46 ≈ 0.522).
- D: Propane's carbon fraction (36/44 ≈ 0.818) is less than octane's.
Final answer: C
Topic: Atoms, molecules and stoichiometry
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