O Levels Chemistry (5070)•5070/12/O/N/24

Explanation
Oxidation of copper anode in electrolysis
Steps:
- Anode undergoes oxidation, releasing electrons.
- Pure copper electrodes mean the copper anode dissolves, forming Cu²⁺ ions.
- Solution contains Cu²⁺ and Ag⁺, but no silver metal for oxidation.
- Nitrate ions do not oxidize preferentially over the copper electrode.
Why A is correct:
- Represents oxidation of Cu atoms from the anode to Cu²⁺ ions, following the standard half-equation for copper electrode dissolution.
Why the others are wrong:
- B: Describes reduction of Cu²⁺ to Cu, which occurs at the cathode.
- C: Oxidation of Ag to Ag⁺, but no silver metal is present in the setup.
- D: Reduction of Ag⁺ to Ag, a cathode reaction.
Final answer: A
Topic: Electrolysis
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