O Levels Chemistry (5070)•5070/11/O/N/24

Explanation
Identifying carboxylic acid from molecular formula and acidity
Steps:
- Molecular formula C4H8O2 fits carboxylic acids (general formula CnH2nO2) or esters.
- Turns damp litmus red, indicating acidity from ionizable H+ (carboxylic acids react with water to form H3O+).
- Exclude esters (neutral, no acidic H).
- For C4H8O2, straight-chain carboxylic acid is butanoic acid; displayed formula shows CH3-CH2-CH2-COOH structure.
Why D is correct:
- D displays CH3-CH2-CH2-COOH, matching C4H8O2 and acidic -COOH group (pKa ~4.8, turns litmus red).
Why the others are wrong:
- A: Ester (e.g., CH3COOCH2CH3), neutral, does not turn litmus red.
- B: Ester (e.g., CH3CH2COOCH3), neutral, lacks acidic proton.
- C: Branched acid (e.g., (CH3)2CHCOOH), acidic but displayed formula differs from straight chain.
Final answer: D
Topic: Carboxylic acids
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