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O Levels Chemistry (5070)•5070/11/O/N/23
Question 15 from 5070/11/O/N/23

Explanation

Enthalpy change via bond energies Steps:

  • Bonds broken: H-H (436 kJ/mol) and Br-Br (193 kJ/mol); total input = 436 + 193 = 629 kJ/mol.
  • Bonds formed: 2 H-Br (366 kJ/mol each); total output = 2 × 366 = 732 kJ/mol.
  • ΔH = energy to break bonds - energy from forming bonds = 629 - 732 = -103 kJ/mol. Why B is correct:
  • Matches ΔH formula: endothermic bond breaking minus exothermic bond forming yields negative value for exothermic reaction. Why the others are wrong:
  • A: Wrong sign; ignores net energy release.
  • C: Wrong sign; calculation shows energy release, not absorption.
  • D: Only H-H energy; ignores Br-Br and H-Br contributions.

Final answer: B

Topic: Exothermic and endothermic reactions

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