O Levels Chemistry (5070)•5070/12/O/N/22

Explanation
Le Chatelier's principle determines equilibrium shifts Steps:
- The reaction 2SO₂(g) + O₂(g) ⇌ 2SO₃(g) is exothermic (ΔH = -196 kJ/mol), with 3 moles of gas on left and 2 on right.
- Adding O₂ increases reactant concentration, shifting equilibrium right to consume it.
- Adding SO₃ increases product concentration, shifting equilibrium left to consume it.
- Increasing pressure favors fewer gas moles (right side), shifting right; increasing temperature favors endothermic direction (left).
Why B and D are correct:
- B: Adding SO₃ raises product concentration, so equilibrium shifts left per Le Chatelier's principle to counteract the change.
- D: For exothermic reaction, increasing temperature shifts equilibrium left (endothermic direction) to absorb heat, per Le Chatelier's principle.
Why the others are wrong:
- A: Adding O₂ raises reactant concentration, shifting equilibrium right.
- C: Increasing pressure shifts equilibrium right toward fewer gas moles.
Final answer: B and D
Topic: Reversible reactions and equilibrium
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