O Levels Chemistry (5070)•5070/12/O/N/22

Explanation
Catalysts speed up reactions by lowering activation energy
Steps:
- Identify the reaction as an equilibrium: 2SO₂ + O₂ ⇌ 2SO₃ in the Contact process.
- Recall that catalysts provide an alternative pathway for the reaction without being consumed.
- Determine the catalyst's role: it affects rate, not position of equilibrium.
- Match to options: only lowering activation energy fits the definition.
Why A is correct:
- Catalysts lower the activation energy (E_a), the minimum energy needed for reactants to form products, speeding up the rate as per the Arrhenius equation: rate constant k = A e^(-E_a/RT).
Why the others are wrong:
- B: The catalyst (V₂O₅) facilitates oxidation but does not directly oxidize SO₂ itself.
- C: The reaction oxidizes SO₂ to SO₃; reduction would produce SO₂, opposite of the process.
- D: Catalysts increase rates of both forward and reverse reactions equally, so equilibrium position (K_c) remains unchanged.
Final answer: A
Topic: Rate of reaction
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