O Levels Chemistry (5070)•5070/11/O/N/22

Explanation
Weighted Average Atomic Mass
Steps:
- The atomic mass of 35.5Cl is the weighted average of isotope masses and abundances.
- Let x = % of ^{35}Cl; then (100 - x) = % of ^{37}Cl.
- Set up equation: [35x + 37(100 - x)] / 100 = 35.5.
- Solve: 35x + 3700 - 37x = 3550 → -2x = -150 → x = 75% (so 25% ^{37}Cl).
Why D is correct:
- 75% ^{35}Cl and 25% ^{37}Cl yield (35 × 0.75 + 37 × 0.25) = 35.5, matching the given value.
Why the others are wrong:
- A: Yields average of 36.5, higher than 35.5.
- B: Yields average of 36.2, higher than 35.5.
- C: Yields average of 36, higher than 35.5.
Final answer: D
Topic: Isotopes
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