O Levels Chemistry (5070)•5070/11/O/N/22

Explanation
Catalysts speed up reversible reactions without shifting equilibrium
Steps:
- Catalysts lower activation energy for both forward and reverse reactions equally, increasing rate but not changing equilibrium position.
- Iron is a known catalyst for hydrogen reactions, such as in hydrogenation or ammonia synthesis.
- Aluminum does not typically catalyze reactions involving solids and hydrogen due to its protective oxide layer.
- Thus, only iron catalyzes the reaction, with no effect on equilibrium position.
Why D is correct:
- Catalysts do not alter the equilibrium constant (K), as they affect rates equally; this follows from the definition that equilibrium position depends on K, unchanged by catalysts.
Why the others are wrong:
- A: Aluminum does not catalyze, and no catalyst shifts equilibrium right.
- B: Iron does catalyze, so not both have no effect.
- C: Only iron catalyzes, not both, and equilibrium does not move right.
Final answer: D
Topic: Reversible reactions and equilibrium
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