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O Levels Chemistry (5070)•5070/12/O/N/21
Question 39 from 5070/12/O/N/21

Explanation

Carboxylic acids' characteristic reactions

Steps:

  • Recall that carboxylic acids have the functional group -COOH and undergo specific reactions like esterification.
  • Evaluate each option against known properties: oxidation, unsaturation tests, ester formation, and reaction with bases.
  • Identify that esterification with alcohols is a defining reaction for carboxylic acids.
  • Confirm no other option accurately describes a standard carboxylic acid property.

Why C is correct:

  • Carboxylic acids react with alcohols in the presence of an acid catalyst to form esters via the esterification reaction: RCOOH + R'OH → RCOOR' + H₂O.

Why the others are wrong:

  • A: Carboxylic acids are prepared by oxidation of primary alcohols or aldehydes, not alkanes.
  • B: They do not decolourise bromine water, as they lack carbon-carbon double bonds; alkenes do.
  • D: They react with carbonates to form a salt, carbon dioxide, and water, not hydrogen.

Final answer: C

Topic: Carboxylic acids

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