O Levels Chemistry (5070)•5070/12/O/N/21

Explanation
Object must be cathode for electroplating Steps:
- Identify setup: Steel key in copper(II) sulfate solution with electrical connections for plating.
- Recall electroplating: Cathode (negative) receives metal ions and gets plated; anode (positive) dissolves.
- Diagnose issue: Key not plating means it's likely connected as anode, repelling Cu²⁺ ions.
- Solution: Swap connections so key becomes cathode, attracting Cu²⁺ ions to deposit copper.
Why D is correct:
- Reversing connections makes the key the cathode, where reduction (Cu²⁺ + 2e⁻ → Cu) occurs per Faraday's laws of electrolysis.
Why the others are wrong:
- A: Higher concentration increases ion availability but won't fix wrong polarity preventing deposition.
- B: Sulfuric acid lacks Cu²⁺ ions, so no copper plating possible; it's for cleaning, not plating.
- C: Identical to D, so redundant and doesn't apply uniquely.
Final answer: D
Topic: Electrolysis
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