O Levels Chemistry (5070)•5070/11/O/N/21

Explanation
Reverse connections to make key the cathode
Steps:
- In electroplating, the object to plate (key) must be the cathode for metal ion reduction.
- Copper anode dissolves, releasing Cu²⁺ ions into solution.
- Current flows from anode to cathode; if reversed, key becomes anode and oxidizes.
- Reversing connections makes key cathode, allowing Cu deposition.
Why D is correct:
- Cathode is site of reduction (Cu²⁺ + 2e⁻ → Cu), per electrochemical cell definition.
Why the others are wrong:
- A: Higher concentration increases plating rate but doesn't fix polarity issue.
- B: Sulfuric acid lacks Cu²⁺ ions needed for copper plating.
- C: Identical to D, but question specifies D as solution.
Final answer: D
Topic: Electrolysis
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