O Levels Chemistry (5070)•5070/12/O/N/20

Explanation
Identifying the structure of ethanoic anhydride
Steps:
- Recall that ethanoic anhydride is the dehydrated form of ethanoic acid, with formula (CH₃CO)₂O.
- Examine each option for the anhydride functional group: two acyl groups linked by an oxygen atom.
- Verify the carbon-oxygen-carbon linkage without hydroxyl groups typical of carboxylic acids.
- Confirm the molecular formula matches C₄H₆O₃ with correct bonding.
Why B is correct:
- Option B shows the exact structure CH₃C(O)OC(O)CH₃, matching the definition of an acid anhydride as RCO- O -COR'.
Why the others are wrong:
- A depicts an ester (CH₃COOCH₃), with single carbonyl and alkoxy group, not dual acyl linkage.
- C shows ethanoic acid (CH₃COOH), featuring a hydroxyl group instead of anhydride bridge.
- D represents a symmetric ether (CH₃OCH₃), lacking carbonyl groups entirely.
Final answer: B
Topic: Formulae, functional groups and terminology
Practice more O Levels Chemistry (5070) questions on mMCQ.me