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O Levels Chemistry (5070)•5070/12/O/N/20
Question 31 from 5070/12/O/N/20

Explanation

Electrodes in Hall-Héroult Aluminum Extraction

Steps:

  • Bauxite ore is purified and dissolved in molten cryolite as the electrolyte for electrolysis.
  • Carbon-based electrodes are used: anode oxidizes, releasing oxygen that reacts with carbon to form CO2.
  • Anode must be inert and heat-resistant to avoid contamination.
  • Cathode reduces aluminum ions to molten aluminum metal.

Why A is correct:

  • Graphite serves as the inert anode, conducting electricity and resisting oxidation at high temperatures (around 950°C), per the electrolysis cell design.

Why the others are wrong:

  • B: Steel corrodes rapidly due to oxygen evolution at the anode.
  • C: Bauxite is the aluminum ore (Al2O3 source), not an electrode material.
  • D: Cryolite (Na3AlF6) is the flux to lower melting point of the electrolyte, not an electrode.

Final answer: A

Topic: Electrolysis

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