O Levels Chemistry (5070)•5070/12/O/N/20

Explanation
Electrodes in Hall-Héroult Aluminum Extraction
Steps:
- Bauxite ore is purified and dissolved in molten cryolite as the electrolyte for electrolysis.
- Carbon-based electrodes are used: anode oxidizes, releasing oxygen that reacts with carbon to form CO2.
- Anode must be inert and heat-resistant to avoid contamination.
- Cathode reduces aluminum ions to molten aluminum metal.
Why A is correct:
- Graphite serves as the inert anode, conducting electricity and resisting oxidation at high temperatures (around 950°C), per the electrolysis cell design.
Why the others are wrong:
- B: Steel corrodes rapidly due to oxygen evolution at the anode.
- C: Bauxite is the aluminum ore (Al2O3 source), not an electrode material.
- D: Cryolite (Na3AlF6) is the flux to lower melting point of the electrolyte, not an electrode.
Final answer: A
Topic: Electrolysis
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