O Levels Chemistry (5070)•5070/12/O/N/20

Explanation
Hydrolysis of ethanoic anhydride and esterification
Steps:
- Ethanoic anhydride, (CH₃CO)₂O, hydrolyzes with water to yield 2 mol ethanoic acid: (CH₃CO)₂O + H₂O → 2 CH₃COOH.
- The reaction requires 1 mol water per 1 mol anhydride based on balanced equation.
- The carboxylic acid, CH₃COOH, reacts with ethanol, C₂H₅OH, in esterification: CH₃COOH + C₂H₅OH → CH₃COOC₂H₅ + H₂O.
- Ester structure is CH₃COOCH₂CH₃ (ethyl ethanoate).
Why B is correct:
- B pairs 1 mol water (matches hydrolysis stoichiometry) with ethyl ethanoate structure.
Why the others are wrong:
- A: Incorrect ester structure despite correct water moles.
- C: 2 mol water overstates hydrolysis; only 1 mol needed.
- D: 2 mol water and wrong ester structure.
Final answer: B
Topic: Carboxylic acids
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