O Levels Chemistry (5070)•5070/11/O/N/20

Explanation
Limestone's role in removing impurities during iron extraction
Steps:
- Haematite (Fe2O3) is reduced to iron using coke as a reducing agent in the blast furnace.
- Limestone (CaCO3) is added to handle impurities like silica (SiO2) in the ore.
- Heat causes limestone to decompose: CaCO3 → CaO + CO2.
- Calcium oxide (CaO) reacts with acidic silica to form slag: CaO + SiO2 → CaSiO3, which is removed.
Why A is correct:
- Limestone decomposes to calcium oxide, a base that neutralizes acidic impurities like silica per the acid-base reaction CaO + SiO2 → CaSiO3 (slag).
Why the others are wrong:
- B: Coke provides the fuel and heat; limestone acts as a flux, not a fuel.
- C: Coke burns with oxygen from air blasts; limestone does not release oxygen.
- D: Haematite's iron is already oxidized and needs reduction, not further oxidation.
Final answer: A
Topic: Extraction of metals
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