O Levels Chemistry (5070)•5070/11/O/N/20

Explanation
Metal Reactivity and Displacement Reactions
Steps:
- Consult the reactivity series: silver is below copper, making silver less reactive.
- In aqueous copper(II) sulfate, Cu²⁺ ions are present; a more reactive metal would displace copper, but silver cannot.
- Compare standard electrode potentials: Ag⁺/Ag (+0.80 V) > Cu²⁺/Cu (+0.34 V), so the reaction Ag + Cu²⁺ → Ag⁺ + Cu is not spontaneous.
- Therefore, no displacement or other visible change occurs.
Why B is correct:
- The reactivity series shows silver is less reactive than copper, preventing displacement per the electrochemical series law.
Why the others are wrong:
- A: No gas evolution, as this is not an acid-base or redox gas-producing reaction.
- C: Copper deposition requires a more reactive metal like zinc, not silver.
- D: Silver does not dissolve, lacking sufficient reducing power against Cu²⁺.
Final answer: B
Topic: Reactivity series
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