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O Levels Chemistry (5070)•5070/12/O/N/19
Question 34 from 5070/12/O/N/19

Explanation

Electrophilic addition of bromine to butene forms a vicinal dibromide

Steps:

  • Butene (C4H8) is an alkene with a C=C double bond that undergoes electrophilic addition with Br2.
  • Br2 approaches the double bond, forming a bromonium ion intermediate.
  • A bromide ion then attacks the intermediate, adding Br atoms across the double bond.
  • The product is 1,2-dibromobutane (for 1-butene) or 2,3-dibromobutane (for 2-butene), a vicinal dihalide.

Why B is correct:

  • B represents the vicinal dibromide (e.g., CH3CH2CHBrCH2Br), matching the anti-addition product from the reaction mechanism.

Why the others are wrong:

  • A is a substitution product, but alkenes undergo addition, not substitution with Br2.
  • C is a geminal dibromide, which requires different reagents like NBS, not Br2 addition.
  • D is an unsaturated compound, but the reaction saturates the double bond.

Final answer: B

Topic: Alkenes

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