O Levels Chemistry (5070)•5070/11/O/N/19

Explanation
Percentage yield from stoichiometric hydrogen
Steps:
- Molar mass of H₂ is 2 g/mol; moles of 60 kg H₂ = 60,000 g / 2 = 30,000 mol.
- Reaction: 3 mol H₂ produce 2 mol NH₃ (molar mass 17 g/mol), so 30,000 mol H₂ yield (2/3) × 30,000 = 20,000 mol NH₃.
- Theoretical mass of NH₃ = 20,000 mol × 17 g/mol = 340,000 g = 340 kg.
- Percentage yield = (actual yield / theoretical yield) × 100% = (60 / 340) × 100% ≈ 17.6%.
Why B is correct:
- 17% matches the percentage yield formula applied to the reaction stoichiometry, where actual yield is 60 kg against 340 kg theoretical.
Why the others are wrong:
- A: 5% underestimates yield by ignoring full stoichiometric ratio.
- C: 35% overestimates by misapplying mass ratios.
- D: 50% assumes 1:1 mass proportion, violating the 1:3 H₂:NH₃ mole ratio.
Final answer: B
Topic: The mole and the Avogadro constant
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