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O Levels Chemistry (5070)•5070/11/O/N/19
Question 35 from 5070/11/O/N/19

Explanation

Structural isomers of C4H10O containing an -OH group

Steps:

  • Determine carbon skeletons for C4H10: straight-chain butane (CH3-CH2-CH2-CH3) and branched 2-methylpropane ((CH3)2CH-CH3).
  • Attach -OH to different carbon positions on each skeleton, ensuring the formula remains C4H10O and -OH bonds to a carbon (not hydrogen).
  • List alcohols: butan-1-ol (primary, straight), butan-2-ol (secondary, straight), 2-methylpropan-1-ol (primary, branched), 2-methylpropan-2-ol (tertiary, branched).
  • Count unique structures: four total.

Why C is correct:

  • Alcohols are organic compounds with -OH attached to carbon; C4H10O yields exactly four distinct structural isomers fitting this definition.

Why the others are wrong:

  • A: Excludes branched-chain alcohols, counting only two straight-chain ones.
  • B: Misses the tertiary alcohol, undercounting by one.
  • D: Overcounts by including non-alcohol isomers like ethers (e.g., diethyl ether).

Final answer: C

Topic: Alcohols

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