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O Levels Chemistry (5070)•5070/11/O/N/19
Question 34 from 5070/11/O/N/19

Explanation

Electrophilic addition of Br₂ to the alkene double bond in butene

Steps:

  • Butene (C₄H₈) is an alkene with a C=C bond that undergoes electrophilic addition with Br₂.
  • Br₂ adds across the double bond following Markovnikov's rule, forming a vicinal dibromide.
  • For 1-butene, addition yields 1,2-dibromobutane; for 2-butene, it yields 2,3-dibromobutane.
  • The product is a saturated dibromobutane (C₄H₈Br₂) with Br atoms on adjacent carbons.

Why B is correct:

  • B represents 1,2-dibromobutane, the direct product of anti addition to 1-butene's double bond per the mechanism of electrophilic addition.

Why the others are wrong:

  • A is 1-bromobutane, a substitution product, not addition.
  • C is 1,4-dibromobutane, requiring addition across non-adjacent carbons, impossible in this reaction.
  • D is 2,2-dibromobutane, violating Markovnikov addition to form a geminal dihalide.

Final answer: B

Topic: Alkenes

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