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O Levels Chemistry (5070)•5070/11/O/N/19
Question 17 from 5070/11/O/N/19

Explanation

Redox agents in disproportionation and reaction enthalpy Steps:

  • ΔH = +131 kJ/mol is positive, confirming endothermic reaction.
  • Reaction likely intended as Cl₂(g) + H₂O(g) → HOCl(g) + HCl(g), a disproportionation.
  • Cl oxidation state: 0 in Cl₂ to +1 in HOCl (oxidized) and -1 in HCl (reduced).
  • H₂O supplies oxygen to oxidize part of Cl₂, making H₂O oxidizing agent and Cl₂ reducing agent.

Why C is correct:

  • Endothermic per positive ΔH; H₂O oxidizes Cl (0 to +1) by providing electronegative oxygen, per redox definition where oxidizing agent causes oxidation.

Why the others are wrong:

  • A: Wrongly assigns Cl₂ as oxidizing agent (it's partially oxidized) and H₂O as reducing.
  • B: Misidentifies agents and claims exothermic (ΔH > 0).
  • D: Misidentifies agents and claims exothermic (ΔH > 0).

Final answer: C

Topic: Redox

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