O Levels Chemistry (5070)•5070/11/O/N/18

Explanation
Stronger metallic bonding in lithium
Steps:
- Both lithium and sodium are alkali metals with one valence electron forming a "sea" of delocalized electrons.
- Metallic bonding strength depends on electrostatic attraction between positive ions and the electron sea.
- Lithium ions are smaller than sodium ions due to lower atomic radius in period 2 versus period 3.
- Smaller ions bring positive charges closer to electrons, increasing attraction and requiring more energy to melt.
Why D is correct:
- Metallic bond strength follows Coulomb's law: force increases as distance decreases, so lithium's smaller ions create stronger bonds than sodium's larger ones.
Why the others are wrong:
- A: Both have one valence electron, so equal valency electrons.
- B: Sodium is more reactive due to lower ionization energy, but reactivity doesn't directly affect melting point.
- C: Sodium's softness relates to weaker bonding, but this describes the effect, not the cause.
Final answer: D
Topic: Metallic bonding
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