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O Levels Chemistry (5070)•5070/12/M/J/25
Question 36 from 5070/12/M/J/25

Explanation

Identifying the structure of ethanoic anhydride

Steps:

  • Recall ethanoic anhydride's formula: (CH₃CO)₂O, with two acetyl groups linked by an oxygen.
  • Examine the diagram for a central O atom bonded to two C=O groups, each with CH₃ attached.
  • Verify the molecular formula matches C₄H₆O₃.
  • Confirm no other functional groups like alcohols or carboxylic acids are present.

Why A is correct:

  • Option A depicts the exact anhydride structure with the (CH₃C=O)₂O linkage, matching the IUPAC definition of an acid anhydride.

Why the others are wrong:

  • B shows a carboxylic acid (CH₃COOH), which has an OH group instead of the anhydride linkage.
  • C represents an ester (e.g., CH₃COOCH₃), with an alkoxy group rather than symmetric acyl-oxygen-acyl.
  • D illustrates ethanoic acid dimer or incorrect bonding, violating the anhydride's planar carbonyl arrangement.

Not enough information on exact diagram details, but based on standard structure.

Final answer: A

Topic: Formulae, functional groups and terminology

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