O Levels Chemistry (5070)•5070/12/M/J/25

Explanation
Structural isomers of C4H10O alcohols
Steps:
- Determine possible carbon skeletons: straight chain (butane) and branched (isobutane).
- For straight chain, attach OH to primary (C1) or secondary (C2) carbons, yielding 1-butanol and 2-butanol.
- For branched chain, attach OH to primary carbon of isobutane (2-methyl-1-propanol) or tertiary carbon (2-methyl-2-propanol).
- Confirm no duplicates or additional skeletons fit C4H10O.
Why C is correct:
- Structural isomers differ in carbon connectivity; exactly four alcohols satisfy the formula via distinct OH placements on C4 skeletons.
Why the others are wrong:
- A: Underestimates by ignoring branched chains.
- B: Misses the tertiary alcohol isomer.
- D: Overcounts, as no fifth unique structure exists.
Final answer: C
Topic: Alcohols
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