O Levels Chemistry (5070)•5070/12/M/J/25

Explanation
Reaction rate increases with acid concentration, but total hydrogen volume is identical
Steps:
- Calculate moles: 2.4 g Mg is 0.1 mol; Exp 1 has 0.1 mol H₂SO₄ (100 cm³ × 1.0 mol/dm³), Exp 2 also 0.1 mol (50 cm³ × 2.0 mol/dm³).
- Determine total product: Stoichiometry gives 0.1 mol H₂ (2.24 dm³ at RTP) for both, so same maximum volume.
- Analyze rate: Reaction rate ∝ [H⁺]; Exp 2's 2.0 mol/dm³ acid yields faster initial rate than Exp 1's 1.0 mol/dm³.
- Predict graph: Both curves reach same volume, but Exp 2 is steeper and plateaus sooner.
Why A is correct:
- Matches rate law (rate = k [H₂SO₄]), showing identical total H₂ but faster kinetics for higher concentration.
Why the others are wrong:
- B: Incorrectly shows different maximum volumes, ignoring equal moles of reactants.
- C: Depicts identical rates, violating concentration dependence.
- D: Reverses curves, with lower concentration faster.
Final answer: A
Topic: Rate of reaction
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