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O Levels Chemistry (5070)•5070/11/M/J/25
Question 19 from 5070/11/M/J/25

Explanation

Contact Process Conditions for SO₂ to SO₃

Steps:

  • Identify catalyst: Vanadium(V) oxide accelerates the reaction without being consumed.
  • Recall temperature: 400–450°C optimizes rate and yield for exothermic equilibrium.
  • Recall pressure: 100–200 kPa (1–2 atm) shifts equilibrium right per Le Chatelier's principle.
  • Match options: Select row with correct catalyst and pressure near 200 kPa.

Why D is correct:

  • Vanadium(V) oxide is the standard catalyst; 200 represents ~200 kPa pressure, aligning with typical 1–2 atm to favor product formation.

Why the others are wrong:

  • A: Iron is incorrect catalyst (V₂O₅ used); 2000 kPa is excessively high.
  • B: Vanadium(V) oxide correct, but 200 likely °C (too low for reaction rate).
  • C: Vanadium(V) oxide correct, but 2000 likely °C (impossibly high, would decompose reactants).

Final answer: D

Topic: Reversible reactions and equilibrium

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